In the 1950s, Louis Miller conducted a number of experiments that tried to model the origin of organic compounds in a prebiotic world. Among these was the Miller-Urey experiment, in which a vessel containing water, methane, ammonia and hydrogen was heated and subjected to electrical discharge (simulating lightning). Diagram of the experiment (Wikipedia). At the time, Miller reported that a number of amino acids were formed.
This brief article describes the reanalysis of stored vials containing the outcome of one of these experiments, using material found at the University of Chicago after Miller's death. Apparently Miller had identified five amino acids and a number of unidentified compounds in some of the experiments.